Immobilization on a nanomagnetic Co/C surface using ROM polymerization: Generation of a novel hybrid material as support for a recyclable palladium catalyst
University of Kansas
posted on 03/23/2011
The invention consists of a high load, highly magnetic ROMP material with tunable solubility properties as a readily reusable ligand and/or a catalyst or as a recyclable reagent scavenger. Separation of the material from reaction mixtures only requires decantation with an applied magnetic field, allowing the material to be readily recovered and reused. For magnetic materials that are metal containing catalysts, metal leaching is insignificant. The overall strategy has been demonstrated by constructing a palladium catalyst that is applied in Suzuki coupling reactions where the catalyst can be easily recycled and reused multiple times.
Suggested Uses
- Catalysts
- Ligands (chiral and achiral)
- Scavengers
- High throughput platforms
Advantages
- High-load, soluble ligands, catalysts, and scavengers
- Simple purification through magnetic decantation
- Reduce cost of product separation while retaining homogeneous reactivity profiles
File Number: 11KU001L
| Patent Number(s): | 61/378778 |
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This innovation currently is not available for online licensing. Please contact Matt Koenig at University of Kansas for more information.
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