Highly Efficient Dye-Synsitized Solar Cells Using Microtextured Electron Collecting Anode and Nanoporous and Interdigitated Hole Collecting Cathode and Method for Making Same
Northern Illinois University
posted on 06/24/2010
Nanocrystalline dye-sensitized solar cells (DSSC) are an appealing device for solar-electric energy conversion for its low cost, simple process, and large-scale production. This invention and method for manufacturing radically alters the nature of the electron transport in traditional TiO2 nanoparticle-based DSSC, from semiconducting to metallic conducting, instead of the traditional method of affecting the electron diffusion length through changing shapes of the semiconducting anode. This strategy erects free-standing metallic pillars on transparent conducting oxide (TCO) glass via electrochemical deposition methods. The pillars or microantennas serve as shortcuts and fast lanes for electron transport from nanoparticles to the TCO anode; in a manner analogous to an antenna that collects radio signals. Besides dye-loading, a key to the higher efficiency is the miroantenna pillar shape when arranged in arrays which decreases electron migration distance.
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File Number: C09-004
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